A:Answer No. The schedule "arms" and "disarms" the doorbell. When it is disarmed, it is effectively "off" and won't detect and record.
However, you could silence your phone and/or your doorbell chime during those hours, leave the doorbell armed at all times, and it will record any activity.
Actually, I might have to start silencing my phone at night because a neighbor's cat keeps coming up to our front door at the wee hours of the morning and setting off my phone alert.